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Cr,Tm, Ho:Yttrium Aluminum Garnet¡ªCTH:YAG

CTH:YAG is a new crystal material which lases at 2080 nm. It has applications in medical, military and meteorological fields.

The key to efficient operation lies in the energy transfer processes between co-dopants of Cr,Tm and Ho. Cr3+ acts to effectively absorb flashlamp energy, which is then transferred to theTm3+ with an efficiency of > 90%. A Tm:Tm cross relaxation then occurs and converts this energy into the IR with a quantum efficiency approaching 2, after which the Tm:Tm energy migration facilitates an efficient Tm:Ho energy transfer.

Advantages Of Cr,Tm,Ho:YAG Include:

High-efficiency 2¦Ìm source

  • Cr-Tm transfer quantum efficiency approaching 2
  • Operates well at room temperature
  • May be flashlamp or diode pumped

Laser diode sources can pump the strong 780nm Tm3+ ion absorption line

  • Chromium doping not necessary for diode-pumped applications
  • Pump linewidth of 4 nm; 4 times wider than the corresponding Nd:YAG diode-pump linewidth

Operates in a relatively eye-safe wavelength range

  • Should lead to military and scientific applications in coherent radar and range-finding

Standard Rod Specifications

Common properties

PROPERTY

VALUE

chemical formula

Y3Al5O12:Cr3+, (Tm3+, Ho3+)

crystal structure

10Oh

lattice constant, A

12.00

refractive index n

1.82 (1.0 mm)

dielectric constant

11.7

dn/dT, K-1

7.3 x 10-6

density, g/cm3

4.56

melting point, ¡ãC

1950

specific heat, J/(kg K)

590

thermal conductivity, W/(cm K)

0.13

thermal expansion

8.2 x 10-6 K-1 in [100]
7,7 x 10-6 K-1 in [111]

Knoop Hardness

1215

Element specification

PROPERTY

VALUE

orientation

[100] within 1 degree

dopant level

 ¡À 0.1 %

dimensions

¡À 0.1 (diameter)
¡À 0.5 (length)

wavefront distortion

¡Ü l/4 per inch

flatness

l/10

parallelism

¡Ü 1minute of arc

perpendicularity

¡Ü 10 minutes of arc

scratch-dig

10-5 per MIL-O-13830A

barrel finish

polished or grinded

end coatings (AR at 1,66 µm)

¡Ü0.25 %

 

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